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The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist (Record no. 45486)

MARC details
000 -LEADER
fixed length control field 02935nam a22004937a 4500
001 - CONTROL NUMBER
control field sulb-eb0023394
003 - CONTROL NUMBER IDENTIFIER
control field BD-SySUS
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20160413122349.0
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
fixed length control field cr nn 008mamaa
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 131015s2013 gw | s |||| 0|eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number 9783319016740
-- 978-3-319-01674-0
024 7# - OTHER STANDARD IDENTIFIER
Standard number or code 10.1007/978-3-319-01674-0
Source of number or code doi
050 #4 - LIBRARY OF CONGRESS CALL NUMBER
Classification number QD146-197
072 #7 - SUBJECT CATEGORY CODE
Subject category code PNK
Source bicssc
Subject category code SCI013030
Source bisacsh
082 04 - DEWEY DECIMAL CLASSIFICATION NUMBER
Classification number 546
Edition number 23
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Blusch, Lina K.
Relator term author.
245 14 - TITLE STATEMENT
Title The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist
Medium [electronic resource] /
Statement of responsibility, etc. by Lina K. Blusch.
264 #1 - PRODUCTION, PUBLICATION, DISTRIBUTION, MANUFACTURE, AND COPYRIGHT NOTICE
Place of production, publication, distribution, manufacture Cham :
Name of producer, publisher, distributor, manufacturer Springer International Publishing :
-- Imprint: Springer,
Date of production, publication, distribution, manufacture, or copyright notice 2013.
300 ## - PHYSICAL DESCRIPTION
Extent XVIII, 158 p. 142 illus., 48 illus. in color.
Other physical details online resource.
336 ## - CONTENT TYPE
Content type term text
Content type code txt
Source rdacontent
337 ## - MEDIA TYPE
Media type term computer
Media type code c
Source rdamedia
338 ## - CARRIER TYPE
Carrier type term online resource
Carrier type code cr
Source rdacarrier
347 ## - DIGITAL FILE CHARACTERISTICS
File type text file
Encoding format PDF
Source rda
490 1# - SERIES STATEMENT
Series statement Springer Theses, Recognizing Outstanding Ph.D. Research,
International Standard Serial Number 2190-5053
505 0# - FORMATTED CONTENTS NOTE
Formatted contents note General Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations.
520 ## - SUMMARY, ETC.
Summary, etc. This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Chemistry.
Topical term or geographic name as entry element Inorganic chemistry.
Topical term or geographic name as entry element Bioorganic chemistry.
Topical term or geographic name as entry element Organometallic chemistry.
Topical term or geographic name as entry element Chemistry.
Topical term or geographic name as entry element Inorganic Chemistry.
Topical term or geographic name as entry element Bioorganic Chemistry.
Topical term or geographic name as entry element Organometallic Chemistry.
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element SpringerLink (Online service)
773 0# - HOST ITEM ENTRY
Title Springer eBooks
776 08 - ADDITIONAL PHYSICAL FORM ENTRY
Relationship information Printed edition:
International Standard Book Number 9783319016733
830 #0 - SERIES ADDED ENTRY--UNIFORM TITLE
Uniform title Springer Theses, Recognizing Outstanding Ph.D. Research,
International Standard Serial Number 2190-5053
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="http://dx.doi.org/10.1007/978-3-319-01674-0">http://dx.doi.org/10.1007/978-3-319-01674-0</a>
912 ## -
-- ZDB-2-CMS
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme
Koha item type

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