TY  - BOOK
AU  - Wu,Peng
AU  - Xu,Hao
AU  - Xu,Le
AU  - Liu,Yueming
AU  - He,Mingyuan
ED  - SpringerLink (Online service)
TI  - MWW-Type Titanosilicate: Synthesis, Structural Modification and Catalytic Applications to Green Oxidations 
T2  - SpringerBriefs in Molecular Science,
SN  - 9783642391156
AV  - QD505 
U1  - 541.395 23
PY  - 2013///
CY  - Berlin, Heidelberg
PB  - Springer Berlin Heidelberg, Imprint: Springer
KW  - Chemistry
KW  - Physical chemistry
KW  - Chemical engineering
KW  - Catalysis
KW  - Environmental chemistry
KW  - Environmental Chemistry
KW  - Industrial Chemistry/Chemical Engineering
KW  - Physical Chemistry
N1  - Introduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects
N2  - This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta
UR  - http://dx.doi.org/10.1007/978-3-642-39115-6
ER  -