Electrochemistry of metal complexes : applications from electroplating to oxide layer formation / Arvydas Survila

Includes bibliographical references and index.

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Related Titles; Title Page; Copyright; Table of Contents; Preface; Symbols and Abbreviations; Chapter 1: Introduction; 1.1 Equilibrium Properties of Complex Systems; References; Chapter 2: Equilibrium Electrode Potentials; 2.1 Electrodes of the First Kind; 2.2 Equilibria Involving Ions of the Intermediate Oxidation State; 2.3 Electrodes of the Second Kind; 2.4 Open-Circuit Potentials: Examples of Experimental Investigations; References; Chapter 3: Mass Transport; 3.1 Two Models of Linear Mass Transport; 3.2 Other Cases of Diffusional Mass Transport

3.3 Mass Transport of Chemically Interacting Particles3.4 Concentration Profiles; References; Chapter 4: Peculiarities of Electrochemical Processes Involving Labile Complexes; 4.1 Steady-State Voltammograms; 4.2 Potential Transients; 4.3 Current Transients; References; Chapter 5: Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals; 5.1 Kinetic Equations; 5.2 Employment of Voltammetric Data; 5.3 Techniques Based on the Control of the Intensity of Forced Convection; References

Chapter 6: Determination of Mechanism of Electrochemical Processes Involving Metal Complexes6.1 Determination of the Mechanism by Reaction Orders; 6.2 Method of Isopotential Solutions; References; Chapter 7: Adsorption; 7.1 Thermodynamic Aspects; 7.2 Model Aspects; References; Chapter 8: Electrochemical Processes in Real Systems; 8.1 Experimental Details; 8.2 Cyanide Systems; 8.3 Ecological Systems Containing Hydroxy Acids; Appendix; References; Chapter 9: Electrochemical Deposition of Alloys; 9.1 Mass Transport during the Codeposition of Metals; 9.2 Codeposition of Cobalt and Tin

9.3 Deposition of Brass Coatings9.4 Deposition of Bronze Coatings; 9.5 Codeposition of Cobalt and Molybdenum; References; Chapter 10: Spontaneous Formation of Photosensitive Cuprous Oxide Layers; 10.1 Two Mechanisms of Cu2O Formation; 10.2 Composition of Oxide Layers; 10.3 Kinetics of Cu2O Formation; 10.4 Electrochemical Reduction of Oxide Layers; 10.5 Photoelectrochemical Properties of Oxide Layers; 10.6 Photoelectrochemical Stability of Oxide Layers; 10.7 Influence of Oxide Layers on Kinetics of Cu(II) Reduction; References; Chapter 11: Hydrogen Evaluation Involving Ligands as Proton Donors