000			03170nam a22004937a 4500
001			sulb-eb0023352
003			BD-SySUS
005			20160413122346.0
007			cr nn 008mamaa
008			130809s2013 gw | s |||| 0|eng d
020			_a9783319011349 _9978-3-319-01134-9
024	7		_a10.1007/978-3-319-01134-9 _2doi
050		4	_aQD415-436
072		7	_aPNN _2bicssc
072		7	_aSCI013040 _2bisacsh
082	0	4	_a547 _223
100	1		_aLennox, Alastair J. J. _eauthor.
245	1	0	_aOrganotrifluoroborate Preparation, Coupling and Hydrolysis _h[electronic resource] / _cby Alastair J. J. Lennox.
264		1	_aCham : _bSpringer International Publishing : _bImprint: Springer, _c2013.
300			_aXV, 223 p. 308 illus., 96 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
505	0		_aGeneral Introduction -- Organotrifluoroborate Preparation -- Organotrifluoroborate Coupling -- Organotrifluoroborate Hydrolysis -- Conclusions and Future Work -- Experimental: General Experimental Details -- Experimental: Organotrifluoroborate Preparation -- Experimental: Organotrifluoroborate Coupling -- Experimental: Organotrifluoroborate Hydrolysis.
520			_aAlistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.
650		0	_aChemistry.
650		0	_aOrganic chemistry.
650		0	_aChemical engineering.
650		0	_aCatalysis.
650	1	4	_aChemistry.
650	2	4	_aOrganic Chemistry.
650	2	4	_aCatalysis.
650	2	4	_aIndustrial Chemistry/Chemical Engineering.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783319011332
830		0	_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-319-01134-9
912			_aZDB-2-CMS
942			_2Dewey Decimal Classification _ceBooks
999			_c45444 _d45444