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001 sulb-eb0023394
003 BD-SySUS
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008 131015s2013 gw | s |||| 0|eng d
020 _a9783319016740
_9978-3-319-01674-0
024 7 _a10.1007/978-3-319-01674-0
_2doi
050 4 _aQD146-197
072 7 _aPNK
_2bicssc
072 7 _aSCI013030
_2bisacsh
082 0 4 _a546
_223
100 1 _aBlusch, Lina K.
_eauthor.
245 1 4 _aThe Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist
_h[electronic resource] /
_cby Lina K. Blusch.
264 1 _aCham :
_bSpringer International Publishing :
_bImprint: Springer,
_c2013.
300 _aXVIII, 158 p. 142 illus., 48 illus. in color.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
505 0 _aGeneral Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations.
520 _aThis thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications.
650 0 _aChemistry.
650 0 _aInorganic chemistry.
650 0 _aBioorganic chemistry.
650 0 _aOrganometallic chemistry.
650 1 4 _aChemistry.
650 2 4 _aInorganic Chemistry.
650 2 4 _aBioorganic Chemistry.
650 2 4 _aOrganometallic Chemistry.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783319016733
830 0 _aSpringer Theses, Recognizing Outstanding Ph.D. Research,
_x2190-5053
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-319-01674-0
912 _aZDB-2-CMS
942 _2Dewey Decimal Classification
_ceBooks
999 _c45486
_d45486