000 | 02935nam a22004937a 4500 | ||
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001 | sulb-eb0023394 | ||
003 | BD-SySUS | ||
005 | 20160413122349.0 | ||
007 | cr nn 008mamaa | ||
008 | 131015s2013 gw | s |||| 0|eng d | ||
020 |
_a9783319016740 _9978-3-319-01674-0 |
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024 | 7 |
_a10.1007/978-3-319-01674-0 _2doi |
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050 | 4 | _aQD146-197 | |
072 | 7 |
_aPNK _2bicssc |
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072 | 7 |
_aSCI013030 _2bisacsh |
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082 | 0 | 4 |
_a546 _223 |
100 | 1 |
_aBlusch, Lina K. _eauthor. |
|
245 | 1 | 4 |
_aThe Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist _h[electronic resource] / _cby Lina K. Blusch. |
264 | 1 |
_aCham : _bSpringer International Publishing : _bImprint: Springer, _c2013. |
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300 |
_aXVIII, 158 p. 142 illus., 48 illus. in color. _bonline resource. |
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336 |
_atext _btxt _2rdacontent |
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337 |
_acomputer _bc _2rdamedia |
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338 |
_aonline resource _bcr _2rdacarrier |
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347 |
_atext file _bPDF _2rda |
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490 | 1 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 |
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505 | 0 | _aGeneral Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations. | |
520 | _aThis thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications. | ||
650 | 0 | _aChemistry. | |
650 | 0 | _aInorganic chemistry. | |
650 | 0 | _aBioorganic chemistry. | |
650 | 0 | _aOrganometallic chemistry. | |
650 | 1 | 4 | _aChemistry. |
650 | 2 | 4 | _aInorganic Chemistry. |
650 | 2 | 4 | _aBioorganic Chemistry. |
650 | 2 | 4 | _aOrganometallic Chemistry. |
710 | 2 | _aSpringerLink (Online service) | |
773 | 0 | _tSpringer eBooks | |
776 | 0 | 8 |
_iPrinted edition: _z9783319016733 |
830 | 0 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 |
|
856 | 4 | 0 | _uhttp://dx.doi.org/10.1007/978-3-319-01674-0 |
912 | _aZDB-2-CMS | ||
942 |
_2Dewey Decimal Classification _ceBooks |
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999 |
_c45486 _d45486 |