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_a547/.2 _223 |
| 049 | _aMAIN | ||
| 100 | 1 |
_aSierra, Miguel A. _q(Miguel Angel), _eauthor. |
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| 245 | 1 | 0 |
_aMore dead ends and detours : _ben route to successful total synthesis / _cMiguel A. Sierra, María C. de la Torre, and Fernando P. Cossío. |
| 250 | _aFirst edition. | ||
| 264 | 1 |
_aWeinheim, Germany : _bWiley-VCH Verlag GmbH & Co. KGaA, _c2013. |
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| 264 | 4 | _c©2013 | |
| 300 |
_a1 online resource (xxi, 266 pages) : _billustrations |
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_atext _btxt _2rdacontent |
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_acomputer _bc _2rdamedia |
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| 338 |
_aonline resource _bcr _2rdacarrier |
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| 588 | 0 | _aOnline resource; title from PDF title page (viewed May 7, 2014). | |
| 500 | _aEdition statement from first page of chapter PDFs. | ||
| 504 | _aIncludes bibliographical references and index. | ||
| 520 | 3 | _aSuccess comes in many forms and in synthesis it can be a failure that results in their ultimate successful solutions. This long-awaited sequel to "Dead Ends and Detours" retains the proven concept while featuring over 20 new case studies of failed strategies and their (successful) solutions in natural product total synthesis. Additionally, computational models are used to discuss the problem in much more detail and to provide readers with additional information not found in the primary literature. The topics range from classic synthetic reactions (e.g. Diels Alder reaction), metal-mediated coupling reactions, metathesis, and asymmetric catalysis to the importance of protecting and activating groups. This book will benefit not only graduate students in organic chemistry but also advanced researchers as they gain knowledge derived from the step-by-step analysis of mistakes made in the past and, thus be able to improve their own chemical reaction planning. With its coverage of the most commonly applied reaction types, the book perfectly complements its predecessor, which focuses on general aspects, such as reactivity and selectivity. | |
| 505 | 0 | _aThe Inertia of Conventional Functional Groups -- The Diels-Alder Reaction -- The Aldol Condensation -- Cyclizations: Concerted, Radical, or Polar? -- Macrocycles: From Reluctant Ring Closure to Reluctant Ring Opening -- Stereochemistry, Controlled or Uncontrolled? -- Transition Metal-Mediated Transformations vs "Conventional" Reactions -- When Metathesis Fails -- Oxidations in C-C Bond Building -- The Failure of Epoxide Ring Opening and the Limits of Cascade Reactions. | |
| 650 | 0 |
_aOrganic compounds _xSynthesis. |
|
| 650 | 7 |
_aSCIENCE _xChemistry _xOrganic. _2bisacsh |
|
| 650 | 7 |
_aOrganic compounds _xSynthesis. _2fast _0(OCoLC)fst01047668 |
|
| 655 | 4 | _aElectronic books. | |
| 655 | 7 |
_aElectronic books. _2local |
|
| 700 | 1 |
_aTorre, María C. de la, _eauthor. |
|
| 700 | 1 |
_aCossío, Fernando P., _eauthor. |
|
| 776 | 0 | 8 |
_iPrint version: _aSierra, Miguel A. _tMore dead ends and detours. _dWeinheim : Wiley-Vch, 2013 _z3527329765 _w(OCoLC)823380609 |
| 856 | 4 | 0 |
_uhttp://onlinelibrary.wiley.com/book/10.1002/9783527654628 _zWiley Online Library [Free Download only for SUST IP] |
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